Articles
The effect of aging at various temperatures on the size, morphology of the strengthening particles of the γʹ-phase and the mechanical properties of the heat-resistant wrought nickel superalloy VZh175-ID was studied. It is shown that the hardening effect during aging at different temperatures varies and depends on the microstructure which formed in the alloy VZh175-ID superalloy at the quenching stage. The excellent tensile strength and strength to rupture is achieved when small spherical or cuboid secondary γʹ-phase and nanosized tertiary γʹ-phase are formed in the structure.
2. Kablov E.N. Materialy novogo pokoleniya [Generation Materials] // Zashchita i bezopasnost. 2014. №4. S. 28–29.
3. Kablov E.N., Alekseyev A.A. Fizika zharoprochnosti geterofaznykh splavov [Physics of heat resistance of heterophase alloys] // Liteynyye zharoprochnyye splavy. Effekt S.T. Kishkina. M.: Nauka, 2006. S. 44–55.
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11. Mao J., Chang K.M., Yang W. et al. Cooling precipitation and strengthening study in powder metallurgy superalloy U720LI // Metallurgical and materials transaction A. 2001.Vol. 32. Issue 10. P. 2441–2452.
12. Perrut M., Locq D. ʹ precipitation kinetics in the powder metallurgy superalloy N19 and influence of the precipitation latent heat // MATEC Web of Congerences. 2014. Available at: https://www.matec-conferences.org/ (accessed: August 25, 2019). DOI: 10.1051/matecconf/20141409004.
13. Letnikov M.N., Lomberg B.S., Ospennikova O.G., Bakradze M.M. Vliyaniye skorosti okhlazhdeniya pri zakalke na mikrostrukturu i svoystva zharoprochnogo deformiruyemogo nikelevogo splava VZH175-ID [influence of quench rate on microstructure and mechanical properties of nickel-based wrought superalloy VZh175-ID] // Aviacionnye materialy i tehnologii. 2019. №2 (55). S. 21–30. DOI: 10.18577/2071-9140-2019-0-2-21-30.
14. Baillif P., Lamesle P., Delagnes D. et al. Influence of the quenching rate and step-wise cooling temperatures on microstructural and tensile properties of PER72 Ni-based superalloy. Available at: https://www.matec-conferences.org (accessed: August 25, 2019). DOI: 10.1051/matecconf/20141421002.
15. Xu C., Liu F., Huang L., Jiang. L. Dependance of creep performance and microstructure evolution on solution cooling rate in a polycrcystalline superalloy // Metals. 2018. Vol. 8. Issue 1. Available at: www.mdpi.com/jornal/metals (accessed: August 25, 2019). DOI: 10.3390/met8010004.
16. Gabb T.P., Garg A., Ellis D.L., OʹConnor K.M. Detailed microstructural characterization of the disk alloy ME3. Available at: https://ntrs.nasa.gov (accessed: August 25, 2019).
17. Mitchell R.J., Hardy M., Preuss M., Tin S. Development of ʹ morfology in P/M rotor disc alloys during heat treatment // Superalloys 2004. The Minerals, Metals & Materials Society, 2004. P. 361–370.
18. Mitchell R.J., Preuss M. Inter-Relationships between Composition, ʹ Morphology, Hardness, and -ʹ Mismatch in Advanced Polycrystalline Nickel-Base Superalloys during Aging at 800°C // Metallurgical and Materials Transactions A. 2007. Vol. 38A. P. 615–627.
19. Mitchell R.J., Preuss M., Tin S., Hardy M. The influence of cooling rate from temperatures above yʹ solvus on morphology, mismatch and hardness in advanced polycrystalline nickel-base superalloys // Materials Science and Engineering A. 2008. Vol. 473. Issues 1–2. P. 158–165.
20. Lomberg B.S., Ovsepyan S.V., Bakradze M.M. Novyy zharoprochnyy nikelevyy splav dlya diskov gazoturbinnykh dvigateley (GTD) i gazoturbinnykh ustanovok (GTU) [New heat-resistant nickel alloy for disks of gas turbine engines (GTE) and gas turbine units (GTU)] // Materialovedeniye. 2010. №7. S. 24–28.
21. Lomberg B.S., Ovsepyan S.V., Bakradze M.M., Mazalov I.S. Vysokotemperaturnye zharo-prochnye nikelevye splavy dlya detalej gazoturbinnyh dvigatelej [High-temperature heat resisting nickel alloys for details of gas turbine engines] // Aviacionnye materialy i tehnologii. 2012. №S. S. 52–57.
22. Kablov E.N. VIAM: materialy novogo pokoleniya dlya PD-14 [VIAM: new generation materials for PD-14] // Krylya Rodiny. 2019. №7–8. S. 54–58.
23. Belyaev M.S., Terentev V.F., Gorbovec M.A., Bakradze M.M., Goldberg M.A. Malociklovaya ustalost pri zadannoj deformacii i parametry uprugoplasticheskogo deformirovaniya zharoprochnogo splava VZh175 [Low-cycle fatigue for a given deformation and parameters of elastic-plastic deformation of superalloy VZh175] // Aviacionnye materialy i tehnologii. 2014. №S4. S. 87–92. DOI: 10.18577/2071-9140-2014-0-s4-87-92.
24. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
25. Chen Y., Prasath R., Slater T.J.A. et al. An investigation of diffusion – mediated cyclic coarsening and reversal coarsening in an advanced Ni-based superalloy // Acta Materialia. 2016. Vol. 110. P. 295–305.
26. Goodfellow A.J., Galindo-Nava E.I., Christofidou K.A. et al. Gamma Prime Precipitate Evolution During Aging of a Model Nickel-Based Superalloy // Metallurgical and materials transaction A. 2018. Vol. 49A. P. 718–728. Available at: http://www.link.springer.com (accessed: August 25, 2019). DOI: 10.1007/s11661-017-4336-y.
The article compares the possibilities of x-ray swing and Laue methods for mass control of the structure perfection of single-crystal castings of nickel heat-resistant alloys. It is concluded that both methods give similar results in determining the axial orientation of single crystals. In determining the misalignment of the block substructure, the swing method allows us to find the axial deviation of each block relative to the Z axis of the sample, that is, relative to the direction of the main acting voltage, and the Laue method allows us to calculate the angles of disorientation of the blocks relative to the orientation of the main crystal. The advantage of the method of Laue in determining the angle of disorientation blocks, as it allows you to test the disorientation of casting blocks of complex shape.
2. Kablov E.N., Sidorov V.V., Kablov D.E., Min P.G. Metallurgicheskie osnovy obespecheniya vysokogo kachestva monokristallicheskih zharoprochnyh nikelevykh splavov [The metallurgical fundamentals for high quality maintenance of single crystal heat-resistant nickel alloys] // Aviacionnye materialy i tehnologii. 2017. №S. S. 55–71. DOI: 10.18577/2071-9140-2017-0-S-55-71.
3. Tolorayya V.N., Kablov E.N., Demonis I.M. Tekhnologiya polucheniya monokristallicheskikh otlivok turbinnykh lopatok GTD zadannoy kristallograficheskoy oriyentatsii iz reniysoderzhashchikh zharoprochnykh splavov [The technology for producing single-crystal castings of turbine engine turbine blades of a given crystallographic orientation from rhenium-containing heat-resistant alloys] // Liteynye zharoprochnyye splavy. Effekt S.T. Kishkina. M.: Nauka, 2006. S. 206–219.
4. Kablov E.N., Bondarenko Yu.A., Kablov D.E. Osobennosti struktury i zharoprochnyh svojstv monokristallov <001> vysokorenievogo nikelevogo zharoprochnogo splava, poluchennogo v usloviyah vysokogradientnoj napravlennoj kristallizacii [Features of structure and heat resisting properties of monocrystals of <001> high-rhenium nickel hot strength alloys received in the conditions of high-gradient directed crystallization] // Aviacionnye materialy i tehnologii. 2011. №4. S 25–31.
5. Kablov E.N., Bondarenko Yu.A., Echin A.B. Issledovaniye vliyaniya peremennogo upravlyayemogo temperaturnogo gradiyenta na osobennosti struktury, fazovyy sostav, svoystva vysokotemperaturnykh zharoprochnykh splavov pri ikh napravlennoy kristallizatsii [Investigation of the influence of a variable controlled temperature gradient on structural features, phase composition, and properties of high-temperature heat-resistant alloys during their directed crystallization] // Vestnik MGTU im. N.E. Baumana. Ser.: Mashinostroyeniye. 2016. №6 (111). S. 43–61.
6. Toloraya V.N., Kablov E.N., Svetlov I.L., Orekhov N.G., Golubovskiy E.R. Anizotropiya prochnostnykh kharakteristik monokristallov nikelevykh zharoprochnykh splavov [Anisotropy of the strength characteristics of single crystals of nickel heat-resistant alloys] // Gornyy informatsionno-analiticheskiy byulleten. 2005. Spetsvypusk. S. 225–236.
7. Toloraya V.N., Kablov E.N., Orekhov N.G., Ostroukhova G.A. Struktura i rostovyye defekty monokristallov nikelevykh zharoprochnykh splavov [Structure and growth defects of single crystals of heat-resistant nickel alloys] // Gornyy informatsionno-analiticheskiy byulleten. 2005. Spetsvypusk. S. 190–202.
8. Nazarkin R.M., Kolodochkina V.G., Ospennikova O.G., Orlov. M.R. Izmeneniya mikrostruktury monokristallov zharoprochnyh nikelevyh splavov v processe dlitelnoj ekspluatacii turbinnyh lopatok [The microstructure modifications of single crystals of Ni-based superalloys in time-tested turbine blades] // Aviacionnye materialy i tehnologii. 2016. №4 (45). S. 9–17. DOI: 10.18577/2071-9140-2016-0-4-9-17.
9. Nazarkin R.M. Rentgenodifrakcionnye metodiki precizionnogo opredeleniya parametrov kristallicheskih reshetok nikelevyh zharoprochnyh splavov (kratkij obzor) [X-ray diffraction techniques for precise determination of lattice constants in Ni-based superalloys: a brief review] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 41–48. DOI: 10.18577/2071-9140-2015-0-1-41-48
10. Khayutin S.G. O razoriyentatsii zeren pri napravlennoy kristallizatsii [On the disorientation of grains in directed crystallization] // Metallovedeniye i termicheskaya obrabotka metallov. 2007. №6. S. 42–43.
11. Sidokhin E.F., Sidokhin F.A., Khayutin S.G. O substrukture monokristallicheskikh lopatok GTD [About the substructure of single-crystal GTE blades] // Aviatsionnaya promyshlennost. 2009. №1. S. 34–36.
12. Sidokhin F.A., Sidokhin A.F., Sidokhin E.F. Ob opredelenii kristallograficheskoy oriyentatsii monokristallov metodom Laue [On the determination of the crystallographic orientation of single crystals by the Laue method] // Zavodskaya laboratoriya. Diagnostika materialov. 2009. T. 75. №1. S. 35–37.
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15. Potrakhov N.N., Khayutin S.G., Lifshits V.A., Oses R. Ustanovka PRDU-KROS dlya ekspressnogo opredeleniya kristallograficheskoy oriyentatsii kubicheskikh monokristallov po obratnym lauegrammam [Installation of PRDU-CROS for the express determination of the crystallographic orientation of cubic single crystals by inverse lauegrams] // Zavodskaya laboratoriya. Diagnostika materialov. 2015. T. 81. №8. S. 27–30.
16. Oses R., Lifshits V.A., Potrakhov E.N., Potrakhov N.N. Programma rasshifrovki obratnykh lauegramm GTSK-monokristallov dlya opredeleniya kristallograficheskoy oriyentatsii obraztsov (KGO-analiz): svid. o gos. reg. Programmy dlya EVM. №201164448 [The decoding program for the inverse lauagrams of fcc single crystals to determine the crystallographic orientation of the samples (KGO analysis): certificate. about state reg. Computer Programs. No. 2011164448]. 2011.
The article presents the results of the development a manufacturing technology for the construction type «blisk» design constructed with a permanent joint with the method of a high-temperature diffusion brazing. The brazing alloy for brazing nickel-based superalloys in bimetallic combinations, that provide a long-term strength of the brazing joint at the level of strength 0,8–0,9 from the least durable of the materials was developed. The influence of heat treatment on microstructure and strength of the brazing joint was investigated. The technology of brazing bimetallic nickel-based superalloys for «blisk» design was developed. Test of a bimetallic specimen of a «blisk» design demonstrator was carried out.
2. Inozemtsev A.A., Nikhamkin M.A., Sandratskiy V.L. Gazoturbinnyye dvigateli. Osnovy konstruirovaniya aviatsionnykh dvigateley i energeticheskikh ustanovok [Gas turbine engines. Fundamentals of designing aircraft engines and power plants]. M.: Mashinostroyeniye, 2007. T. 1: Obshchiye svedeniya. Osnovnyye parametry i trebovaniya. Konstruktivnyye i silovyye skhemy. S. 7–17.
3. Babkin V.I., Tskhovrebov M.M., Solonin V.I., Lanshin A.I. Razvitiye aviatsionnykh GTD i sozdaniye unikal'nykh tekhnologiy [The development of aviation gas turbine engines and the creation of unique technologies] // Dvigatel. 2013. №2 (86). S. 2–7.
4. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation – the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2 (14). S. 16–21.
5. Inozemtsev A.A., Nikhamkin M.A., Sandratskiy V.L. Gazoturbinnyye dvigateli. Osnovy konstruirovaniya aviatsionnykh dvigateley i energeticheskikh ustanovok [Gas turbine engines. Fundamentals of designing aircraft engines and power plants]. M.: Mashinostroyeniye, 2007. T. 2: Kompressory. Kamery sgoraniya. Forsazhnyye kamery. Turbiny. Vykhodnyye ustroystva. S. 259–272.
6. Lunev A.N., Kurylev D.V. Obzor progressivnykh metodov izgotovleniya osevykh monokoles aviatsionnykh gazoturbinnykh dvigateley [A review of progressive manufacturing methods for axial monowheels of aircraft gas turbine engines] // Fundamentalnye issledovaniya. 2016. №6–1. S. 78–82. Available at: http://www.fundamental-research.ru/ru/article/view?id=40375 (accessed: June 18, 2019).
7. Magerramova L.A., Vasilev B.E. Bimetallicheskiye bliski turbin s bandazhirovannymi lopatkami dlya gazoturbinnykh dvigateley [Bimetallic glare of turbines with bandaged blades for gas turbine engines] // Nauka i obrazovaniye: nauchnoye izdaniye MGTU im. N.E. Baumana. 2015. №6. S. 143–156.
8. Yuan J., Scarpa F., Titurus B. et al. Efficient computational techniques for mistuning analysis of bladed discs: a review // Mechanical Systems and Signal Processing. 2017. Vol. 87. Part A. P. 71–90.
9. Magerramova L., Zakharova T., Gromov M., Samarov V. Turbiny: s «blisk»om i bez [Turbines: with and without «blisk»]. Available at: http://engine.aviaport.ru/02page32.html (accessed: Septamber 05, 2019).
10. Kablov E.N., Petrushin N.V., Elyutin E.S. Monokristallicheskiye zharoprochnyye splavy dlya gazoturbinnykh dvigateley [Monocrystalline heat-resistant alloys for gas turbine engines] // Vestnik MGTU im. N.E. Baumana. 2011. Spetsvypusk: Perspektivnyye konstruktsionnyye materialy i tekhnologii. S. 38–52.
11. Povarova K.B., Valitov V.A., Ovsepyan S.V., Drozdov A.A., Bazyleva O.A., Valitova E.V. Izucheniye svoystv i vybor splavov dlya diskov s lopatkami («bliskov») i sposoba ikh soyedineniya [Studying the properties and selection of alloys for blades with blades («blisk») and the method of their connection] // Metally. 2014. №35. S. 61–70.
12. Kablov E.N., Petrushin N.V., Svetlov I.L., Demonis I.M. Nikelevye litejnye zharoprochnye splavy novogo pokoleniya [Nickel foundry heat resisting alloys of new generation] // Aviacionnye materialy i tehnologii. 2012. №S. C. 36–52.
13. Nochovnaya N.A., Bazyleva O.A., Kablov D.E., Panin P.V. Intermetallidnyye splavy na osnove titana i nikelya / pod obshch. red. E.N. Kablova [Intermetallic alloys based on titanium and nickel / gen. ed. E.N. Kablov]. M.: VIAM, 2018. 308 s.
14. Kablov E.N., Petrushin N.V., Svetlov I.L., Demonis I.M. Liteynyye zharoprochnyye splavy novogo pokoleniya [Heat-resistant foundry alloys of a new generation] // 75 let. Aviatsionnyye materialy. M.: VIAM, 2007. S. 27–44.
15. Lomberg B.S., Ovsepjan S.V., Bakradze M.M., Letnikov M.N., Mazalov I.S. Primenenie novyh deformiruemyh nikelevyh splavov dlja perspektivnyh gazoturbinnyh dvigatelej [The application of new wrought nickel alloys for advanced gas turbine engines] // Aviacionnye materialy i tehnologii. 2017. №S. S. 116–129. DOI: 10.18577/2071-9140-2017-0-S-116-129.
16. Lukin V.I., Kovalchuk V.G., Ioda E.N. Svarka plavleniyem – osnova svarochnogo proizvodstva [Fusion welding is a core of welding manufacturing] // Aviacionnyye materialy i tehnologii. 2017. №S. S. 130–143. DOI: 10.18577/2071-9140-2017-0-S-130-143.
17. Ospennikova O.G., Lukin V.I., Afanasev-Khodykin A.N., Galushka I.A. Izgotovleniye konstruktsii tipa «blisk» iz raznoimennogo sochetaniya materialov (obzor) [Manufacturing of design of the «blisk» type from ranoimenny combingtion of materials (review)] // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2018. №10 (70). St. 02. Available at: http://www.viam-works.ru (accessed: July 16, 2019). DOI: 10.18577/2307-6046-2018-0-10-10-16.
18. Magerramova L.A. The advantages of bimetallic blisks manufactured by HIP from powder and cast Ni-base super alloys application to gas turbine with high speed // Proceedings of International Conference on Hot Isostatic Pressing, (HIP02). International Academic Publishers, 2002. P. 59–67.
19. Ospennikova O.G., Lukin V.I., Afanasyev-Khodykin A.N., Galushka I.A., Shevchenko O.V. Perspektivnyye razrabotki v oblasti vysokotemperaturnoy payki zharoprochnykh splavov [Advanced developments in the field of the high-temperature soldering of heat resisting alloys] // Aviacionnyye materialy i tehnologii. 2017. №S. S. 144–158. DOI: 10.18577/2071-9140-2017-0-S-144-158.
20. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
21. Kishkin S.T., Kachanov E.B., Bulygin I.P. Aviacionnye materialy: spravochnik v 9 t. / pod red. R.E. Shalina. 6-e izd., pererab. i dop. [Aviation Materials: a handbook of 9 vol. / ed. R.E. Shalin. 6th ed., rev. and add.]. M.: VIAM, 1989. T. 3: Zharoprochnyye stali i splavy. Splavy na osnove tugoplavkikh metallov. Ch. 1 Deformiruyemyye zharoprochnyye stali i splavy. S. 448–452.
22. Petrunin I.E., Bereznikov Yu.I., Bunkina R.R. i dr. Spravochnik po payke. 3-ye izd. pererab. i dop. [Soldering reference. 3rd ed. rev. and add.]. M.: Mashinostroyeniye-1, 2003. 480 s.
23. Petrunin I.E., Markova I.Yu., Ekatova A.S. Metallovedeniye payki [Metallurgy soldering]. M.: Metallurgiya, 1976. 264 s.
24. Khorunov V.F., Maksimova S.V. Payka zharoprochnykh splavov na sovremennom etape [Brazing of heat-resistant alloys at the present stage] // Svarochnoye proizvodstvo. 2010. №10. S. 24–27.
On the example of an alloy VT20 the problem of solid-metal embrittlement of titanium alloys in contact with silver, zinc and cadmium in the solid state was considered. The influence of the contact density of the surface of titanium alloy with metals, temperature and duration of tests, as well as the application of external tensile stresses were investigated. Temperature thresholds and incubation periods of cracking of VT20 alloy in contact with the studied metals were determined. Studies of fractures of titanium samples and analysis of the chemical composition of their surface after testing were carried out.
2. Kablov E.N. Kompozity: segodnya i zavtra [Composites: today and tomorrow] // Metally Evrazii. 2015. №1. S. 36–39.
3. Podzhivotov N.Yu., Kablov E.N., Antipov V.V., Erasov V.S., Serebrennikova N.Yu., Abdullin M.R., Limonin M.V. Sloistyye metallopolimernyye materialy v elementakh konstruktsii vozdushnykh sudov [Layered metal-polymer materials in aircraft structural elements] // Perspektivnyye materialy. 2016. №10. S. 5–19.
4. Raskutin A.E. Rossiiskie polimernye kompozitsionnye materialy novogo pokoleniia, ikh osvoenie i vnedrenie v perspektivnykh razrabatyvaemykh konstruktsiiakh [Russian polymer composite materials of new generation, their exploitation and implementation in advanced developed constructions] // Aviacionnye materialy i tehnologii. 2017. №S. S. 349–367. DOI: 10.18577/2071-9140-2017-0-S-349-367.
5. Lomberg B.S., Ovsepjan S.V., Bakradze M.M., Letnikov M.N., Mazalov I.S. Primenenie novyh deformiruemyh nikelevyh splavov dlja perspektivnyh gazoturbinnyh dvigatelej [The application of new wrought nickel alloys for advanced gas turbine engines] // Aviacionnye materialy i tehnologii. 2017. №S. S. 116–129. DOI: 10.18577/2071-9140-2017-0-S-116-129.
6. Gromov V.I., Voznesenskaya N.M., Pokrovskaya N.G., Tonysheva O.A. Vysokoprochnye konstrukcionnye i korrozionnostojkie stali FGUP «VIAM» dlya izdelij aviacionnoj tehniki [High-strength constructional and corrosion-resistant steels developed by VIAM for aviation engineering] // Aviacionnye materialy i tehnologii. 2017. №S. S. 159–174. DOI: 10.18577/2071-9140-2017-0-S-159-174.
7. Antipov V.V. Perspektivy razvitiya alyuminievyh, magnievyh i titanovyh splavov dlya izdelij aviacionno-kosmicheskoj tehniki [Prospects for development of aluminium, magnesium and titanium alloys for aerospace engineering] // Aviacionnye materialy i tehnologii. 2017. №S. S. 186–194. DOI: 10.18577/2107-9140-2017-0-S-186-194.
8. Duyunova V.A., Volkova E.F., Uridiya Z.P., Trapeznikov A.V. Dinamika razvitiya magnievyh i litejnyh alyuminievyh splavov [Dynamics of the development of magnesium and cast aluminum alloys] // Aviacionnye materialy i tehnologii. 2017. №S. S. 225–241. DOI: 10.18577/2071-9140-2017-0-S-225-241.
9. Sibileva S.V., Karimova S.A. Obrabotka poverhnosti titanovyh splavov s celyu obespecheniya adgezionnyh svojstv [Surface treatment of titanium alloys to provide adhesion properties] // Aviacionnye materialy i tehnologii. 2013. №S2. S. 25–35.
10. Zakharova L., Botanogov A. Podgotovka poverkhnosti titanovykh splavov VT6ch, VT20 i OT4 dlya povysheniya adgezii lakokrasochnykh pokrytiy [Surface preparation of titanium alloys VT6ch, VT20 and OT4 to increase the adhesion of coatings] // Promyshlennaya okraska. 2013. №4. S. 15–19.
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The properties of VK-51 high-strength film adhesive are given. The effect of reinforcement with nonwoven fabric based on mylar and viscose fibers on the properties of VK-51 adhesive is shown and the properties of reinforced adhesive (VK-51A) are given. A comparison of the properties of VK-51A adhesive with an imported analogue of AF-126 adhesive is given. The effect of the adhesive primer EP-0234 on the resource characteristics of adhesive joints made with VK-51A adhesive in combination with soil is shown.
2. Kablov E.N. Rossiya na rynke intellektualnykh resursov [Russia in the market of intellectual resources] // Ekspert. 2015. №28 (951). S. 48–51.
3. Kablov E.N. Iz chego sdelat budushchee? Materialy novogo pokoleniya, tekhnologii ikh sozdaniya i pererabotki – osnova innovatsiy [What to make the future of? Materials of a new generation, technologies for their creation and processing - the basis of innovation] // Krylya Rodiny. 2016. №5. S. 8–18.
4. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnye plenochnye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
5. Zhadova N.S., Tyumeneva T.Yu., Sharova I.A., Lukina N.F. Perspektivnye tehnologii dlya vremennogo operativnogo remonta aviacionnoj tehniki [Perspective technologies for field repair if aviation engineering] // Aviacionnye materialy i tehnologii. 2013. №2. S. 67–70.
6. Laptev A.B., Barbotko S.L., Nikolaev E.V. Osnovnye napravleniya issledovanij sokhranyaemosti svojstv materialov pod vozdejstviem klimaticheskikh i ekspluatatsionnykh faktorov [The main research areas of the persistence properties of materials under the influence of climatic and operational factors] // Aviacionnye materialy i tehnologii. 2017. №S. S. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
7. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
8. Petrova A.P., Lukina N.F., Pavlyuk B.F., Isaev A.Yu., Besednov K.L. Napolniteli dlya tokoprovodyashchikh kleEv (obzor literatury) [Fillers for conducting glues (literature review)] // Novosti materialovedeniya. Nauka i tekhnika: elektron. nauch.-tekhnich. zhurn. 2017. №5–6 (28). St. 06. Available at: http://www.materialsnews.ru (accessed: August 09, 2019).
9. Petrova A.P., Nikolaev E.V., Lukina N.F., Isaev A.Yu. Klimaticheskaya stoykost kleevykh soedineniy, vypolnennykh epoksidnymi kleyami, v razlichnykh klimaticheskikh zonakh [Climatic resistance of adhesive joints made with epoxy adhesives in various climatic zones] // Klei. Germetiki. Tekhnologii. 2019. №4. S. 16–22.
10. Sorokin A.E., Beyder E.Ya., Perfilova D.N. Vliyanie klimaticheskikh faktorov na svoystva ugleplastika na polifenilensulfidnom svyazuyushchem // Trudy VIAM: elektron. nauch.-tekhnich. zhurn. 2015. №1. St. 10. URL: http://viam-works.ru (data obrashcheniya: 09.08.2019). DOI: 10.18577/2307-6046-2015-0-1-10-10.
11. Sorokin A.E., Bejder E.Ya., Izotova T.F., Nikolaev E.V., Shvedkova A.K. Issledovanie svojstv ugleplastika na polifenilensulfidnom svyazuyushhem posle uskorennyh i naturnyh klimaticheskih ispytanij [Investigation of carbon fiber reinforced plastic on polyphenylenesulfide resin after accelerated and natural climatic test] // Aviacionnye materialy i tehnologii. 2016. №3 (42). S. 66–72. DOI: 10.18577/2071-9140-2016-0-3-66-72.
12. Sytov V.A., Verstakov A.E., Voronin A.E., Sytov V.V. Sovremennye sinteticheskie klei na osnove epoksikauchukovykh kompozitsiy [Modern synthetic adhesives based on epoxy rubber compositions] // Klei. Germetiki. Tekhnologii. 2012. №9. S. 6–9.
13. Sytov V.A., Sytov V.V., Vettegren V.I. Temperaturnaya zavisimost prochnosti kleevykh soedineniy stali na osnove epoksikauchukovykh kleev [Temperature dependence of the strength of adhesive joints of steel based on epoxy rubber adhesives] // Tez. dokl. Mezhdunar. nauch.-tekhnich. konf. «SovremennyE dostizheniya v oblasti kleev i germetikov. Materialy, syre, tekhnologii» (Dzerzhinsk, 17–19 sent., 2013 g.), 2013. S. 50–52.
14. Tkachuk A.I., Terekhov I.V., Kudryavtseva A.N., Grigoreva K.N. Ispolzovanie reologicheskikh metodov issledovaniya pri otverzhdenii epoksidnykh svyazuyushchikh [The use of rheological research methods in the curing of epoxy binders] // Klei. Germetiki. Tekhnologii. 2018. №2. S. 15–20.
15. Tsverava V.G., Rusin M.Yu., Nepovinnykh V.I., Khimitsaev A.S. Analiz vliyaniya uskorennogo klimaticheskogo stareniya na prochnost kleevykh soedineniy [Analysis of the effect of accelerated climatic aging on the strength of adhesive joints] // Klei. Germetiki. Tekhnologii. 2018. №8. S. 28–31.
16. Kochergin Yu.S., Grigorenko T.I. Dinamicheskie mekhanicheskie svoystva epoksidnykh kleevykh kompozitsiy, napolnennykh molotym karbonatom kaltsiya [Dynamic mechanical properties of epoxy adhesive compositions filled with ground calcium carbonate] // Klei. Germetiki. Tekhnologii. 2018. №2. S. 35–44.
17. Petrova A.P., Anikhovskaya L.I. Vliyanie adgezionnogo grunta EP-0234 na svoystva kleevykh soedineniy, vypolnennykh fenolno-kauchukovym kleem VK-50 [Effect of adhesive primer EP-0234 on the properties of adhesive joints made with phenolic-rubber adhesive VK-50] // Klei. Germetiki. Tekhnologii. 2016. №1. S. 19–24.
18. Lukina N.F., Dementeva L.A., Petrova A.P., Anihovskaya L.I. Kleyashhie materialy v konstrukcii lopastej vertoletov [Gluing materials in the design of blades of helicopters] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7. St. 07. Available at: http://www.viam-works.ru (accessed: August 12, 2019). DOI: 10.18577/2307-6046-2016-0-7-7-7.
19. Khrychev Yu.I., Shkodinova E.P., Magin N.A., Dementeva L.A., Khayretdinov R.Kh., Kutsevich K.E. Razrabotka tekhnologicheskogo protsessa izgotovleniya radioprozrachnogo obtekatelya iz kleevykh prepregov tipa KMKS-2M.120 [Development of a technological process for manufacturing a radiolucent fairing from adhesive prepregs of the KMKS-2M.120 type] // Klei. Germetiki. Tekhnologii. 2013. №2. S. 27–30.
20. Startsev V.O., Kutsevich K.E., Khrulev K.A., Molokov M.V. Prognozirovanie temperatury poverkhnosti obraztsov kompozitsionnykh materialov na osnove kleevykh prepregov pri eksponirovanii v klimaticheskikh usloviyakh [Prediction of surface temperature of samples of composite materials based on adhesive prepregs when exposed to climatic conditions] // Klei. Germetiki. Tekhnologii. 2017. №9. S. 24–31.
Reviewed the performance of adhesive joints made of epoxy film adhesives VK-31, VK-41 and MC-51, while the impact of conditions of warm humid climate of Black sea coast and loads of 0.2–0.5 of the original strength of the adhesive joints. It is shown that the level of remaining strength after exposure to the above conditions affects not only the initial strength of the adhesive joints, but also the temperature at which the curing of the adhesive. Adhesive bonding for all three adhesives showed a high level of retained strength after exposure to climatic conditions of warm moist climate of Black sea coast and loads.
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
3. Kablov E.N. Kontrol' kachestva materialov – garantiya bezopasnosti ekspluatatsii aviatsionnoy tekhniki [Quality control of materials - a guarantee of the safety of the operation of aircraft] // Aviacionnyye materialy i tehnologii. 2001. №1. S. 3–8.
4. Sorokin A.E., Bejder E.Ya., Perfilova D.N. Vliyanie klimaticheskih faktorov na svojstva ugleplastika na polifenilensulfidnom svyazuyushhem [Effect of climatic factors on properties of carbon fiber reinforced plastic based on polyphenylenesulfide resin] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №1. St. 10. Available at: http://www.viam-works.ru (accessed: Augusta 12, 2019). DOI: 10.18577/2307-6046-2015-0-1-10-10.
5. Laptev A.B., Barbotko S.L., Nikolaev E.V. Osnovnye napravleniya issledovanij sokhranyaemosti svojstv materialov pod vozdejstviem klimaticheskikh i ekspluatatsionnykh faktorov [The main research areas of the persistence properties of materials under the influence of climatic and operational factors] // Aviacionnye materialy i tehnologii. 2017. №S. S. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
6. Petrova A.P., Lukina N.F., Sharova I.A. Otsenka prochnosti kleyevykh soyedineniy, vypolnennykh epoksidnymi kleyami, pri vozdeystvii razlichnykh faktorov [Strength assessment of adhesive joints made with epoxy adhesives under the influence of various factors] // Vse materialy. Entsiklopedicheskiy spravochnik. 2013. №8. S. 28–34.
7. Sorokin A.E., Bejder E.Ya., Izotova T.F., Nikolaev E.V., Shvedkova A.K. Issledovanie svojstv ugleplastika na polifenilensulfidnom svyazuyushhem posle uskorennyh i naturnyh klimaticheskih ispytanij [Investigation of carbon fiber reinforced plastic on polyphenylenesulfide resin after accelerated and natural climatic test] // Aviacionnye materialy i tehnologii. 2016. №3 (42). S. 66–72. DOI: 10.18577/2071-9140-2016-0-3-66-72.
8. Kochergin Yu.S., Grigorenko T.I. Dinamicheskiye mekhanicheskiye svoystva epoksidnykh kleyevykh kompozitsiy, napolnennykh molotym karbonatom kaltsiya [Dynamic mechanical properties of epoxy adhesive compositions filled with ground calcium carbonate] // Klei. Germetiki. Tekhnologii. 2018. №2. S. 35–44.
9. Lukina N.F., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. Novye razrabotki v oblasti kleyashhih materialov aviacionnogo naznacheniya [New developments in the field of adhesive aviation materials] // Aviacionnye materialy i tehnologii. 2017. №S. S. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
10. Dementyeva L.A., Petrova A.P., Lukina N.F. Primeneniye i naznacheniye epoksidnogo plenochnogo kleya VK-31 [Application and purpose of epoxy film adhesive VK-31] // Vse materialy. Entsiklopedicheskiy spravochnik. 2015. №1. S. 25–29.
11. Dementeva L.A., Bocharova L.I., Lukina N.F., Petrova A.P. Vysokoprochnyye plenochnyye klei VK-51 i VK-51A [High-strength film adhesives VK-51 and VK-51A] // Klei. Germetiki. Tekhnologii. 2015. №4. S. 17–19.
12. Lukina N.F., Dementeva L.A., Petrova A.P., Serezhenkov A.A. Konstrukcionnye i termostojkie klei [Constructional and heat-resistant glues] // Aviacionnye materialy i tehnologii. 2012. №S. S. 328–335.
13. Kablov E.N., Chursova L.V., Lukina N.F., Kutsevich K.E., Rubtsova E.V., Petrova A.P. Issledovaniye epoksidno-polisulfonovykh polimernykh sistem kak osnovy vysokoprochnykh kleyev aviatsionnogo naznacheniya [The study of epoxy-polysulfone polymer systems as the basis of high-strength adhesives for aviation purposes] // Klei. Germetiki. Tekhnologii. 2017. №3. S. 7–12.
14. Sharova I.A. Epoksidnyye klei kholodnogo otverzhdeniya dlya skleivaniya i remonta detaley aviatsionnoy tekhniki: avtoref. diss. … kand. tekhn. nauk [Cold cured epoxy adhesives for gluing and repairing aircraft parts: thesis abstract, Cand. Sc. (Tech.)]. M.: VIAM, 2015. 26 s.
15. Tyumeneva T.Yu., Lukina N.F. Razrabotki v oblasti elastomernykh kleyev aviatsionnogo naznacheniya [Development in the field of elastomeric adhesives for aviation] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №8 (44). St. 9. Available at: http://viam-works.ru (accessed: August 12, 2019). DOI: 10.18577/2307-6046-2016-0-8-9-9.
16. Sytov V.A., Verstakov A.E., Voronin A.E., Sytov V.V. Sovremennyye sinteticheskiye klei na osnove epoksikauchukovykh kompozitsiy [Modern synthetic adhesives based on epoxy rubber compositions] // Klei. Germetiki. Tekhnologii. 2012. №9. S. 6–9.
17. Sytov V.A., Sytov V.V., Vettegren V.I. Temperaturnaya zavisimost prochnosti kleyevykh soyedineniy stali na osnove epoksikauchukovykh kleyev [Temperature dependence of the strength of adhesive joints of steel based on epoxy rubber adhesives] // Tez. dokl. Mezhdunar. nauch.-tekhnich. konf. «Sovremennyye dostizheniya v oblasti kleyev i germetikov. Materialy, syre, tekhnologii» (Dzerzhinsk, 17–19 sent. 2013 g.). Dzerzhinsk, 2013. S. 50–52.
18. Lukina N.F., Dementeva L.A., Petrova A.P., Anihovskaya L.I. Kleyashhie materialy v konstrukcii lopastej vertoletov [Gluing materials in the design of blades of helicopters] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7. St. 07. Available at: http://www.viam-works.ru (accessed: : August 12, 2019). DOI: 10.18577/2307-6046-2016-0-7-7-7.
19. Konoplin A.Yu., Nelyub V.A. Prochnost kleyevykh soyedineniy, izgotovlennykh pri otritsatelnykh znacheniyakh temperatur [Strength of adhesive joints made at negative temperatures] // Klei. Germetiki. Tekhnologii. 2018. №9. S. 20–23.
20. Tkachuk A.I., Gurevich YA.M., Guseva M.A., Mishurov K.S. Tekhnologicheskiye i ekspluatatsionnyye kharakteristiki i oblasti primeneniya epoksidnogo svyazuyushchego VSE-1212, pererabatyvayemogo po prepregovoy tekhnologii [Technological and operational characteristics and applications of the epoxy binder VSE-1212, processed by prepreg technology] // Klei. Germetiki. Tekhnologii. 2018. №4. S. 29–34.
21. Nelyub V.A. Otsenka adgezionnoy prochnosti metodom pull-out v sisteme svyazuyushcheye–elementarnaya nit v zavisimosti ot tipa obrabotki niti [Evaluation of adhesive strength by the pull-out method in a binder – filament system depending on the type of processing of the thread] // Klei. Germetiki. Tekhnologii. 2018. №3. S. 28–32.
22. Tkachuk A.I., Terekhov I.V., Kudryavtseva A.N., Grigoreva K.N. Ispolzovaniye reologicheskikh metodov issledovaniya pri otverzhdenii epoksidnykh svyazuyushchikh [The use of rheological research methods in the curing of epoxy binders] // Klei. Germetiki. Tekhnologii. 2018. №2. S. 15–20.
23. Tsverava V.G., Rusin M.Yu., Nepovinnykh V.I., Khimitsayev A.S. Analiz vliyaniya uskorennogo klimaticheskogo stareniya na prochnost kleyevykh soyedineniy [Analysis of the effect of accelerated climatic aging on the strength of adhesive joints] // Klei. Germetiki. Tekhnologii. 2018. №8. S. 28–31.
The possibility of using ethylene-propylene-diene (SKEPT-40) and methylphenylsiloxane (SKTFV-803) rubbers in the formulation of cold-resistant and ozone-resistant rubber was investigated. The optimal ratio of rubber in the rubber mixture, mixing method and vulcanizing system are proposed. The elastic-strength and thermo cold-resistant characteristics of vulcanizates were determined. It is shown that the investigated rubber based on EPDM and SKTFV has improved physicomechanical and cold-resistant indicators compared to the sealing rubber IRP-1375 based on a mixture of ethylene-propylene and butadiene-styrene rubbers.
2. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsiy, tekhnologicheskogo liderstva i natsionalnoy bezopasnosti Rossii [Materials of a new generation – the basis of innovation, technological leadership and national security of Russia] // Intellekt i tekhnologiya. 2016. №2 (14). S. 16–21.
3. Kablov E.N., Startsev V.O. Sistemnyj analiz vliyaniya klimata na mekhanicheskie svojstva polimernykh kompozitsionnykh materialov po dannym otechestvennykh i zarubezhnykh istochnikov (obzor) [Systematical analysis of the climatics influence on mechanical properties of the polymer composite materials based on domestic and foreign sources (review)] // Aviacionnye materialy i tehnologii. 2018. №2 (51). S. 47–58. DOI: 10.18577/2071-9140-2018-0-2-47-58.
4. Kablov E.N. Materialy i khimicheskiye tekhnologii dlya aviatsionnoy tekhniki [Materials and chemical technologies for aviation technology] // Vestnik Rossiyskoy akademii nauk. 2012. T. 82. №6. S. 520–530.
5. Kablov E.N. Rol khimii v sozdanii materialov novogo pokoleniya dlya slozhnykh tekhnicheskikh sistem [The role of chemistry in the creation of new generation materials for complex technical systems] // Tez. dokl. XX Mendeleyevskogo syezda po obshchey i prikladnoy khimii. Ekaterinburg: UrO RAN, 2016. S. 25–26.
6. Laptev A.B., Barbotko S.L., Nikolaev E.V. Osnovnye napravleniya issledovanij sokhranyaemosti svojstv materialov pod vozdejstviem klimaticheskikh i ekspluatatsionnykh faktorov [The main research areas of the persistence properties of materials under the influence of climatic and operational factors] // Aviacionnye materialy i tehnologii. 2017. №S. S. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
7. Gryaznov V.I., Petrova G.N., Yurkov G.Yu., Buznik V.M. Smesevye termojelastoplasty so specialnymi svojstvami [Thermoplastic mixtures with special properties] // Aviacionnye materialy i tehnologii. 2014. №1. S. 25–29. DOI: 10.18577/2071-9140-2014-0-1-25-29.
8. Eliseev O.A., Krasnov L.L., Zajceva E.I., Savenkova A.V. Razrabotka i modificirovanie elastomernyh materialov dlya primeneniya vo vseklimaticheskih usloviyah [Development and modifying of elastomeric materials for application in all weather conditions] // Aviacionnye materialy i tehnologii. 2012. №S. S. 309–314.
9. Efimov V.A., Shvedkova A.K., Korenkova T.G., Kirillov V.N. Issledovanie polimernyh konstrukcionnyh materialov pri vozdejstvii klimaticheskih faktorov i nagruzok v laboratornyh i naturnyh usloviyah [Research of polymeric constructional materials at influence of climatic factors and loadings in laboratory and natural conditions] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2013. №1. St. 05. Available at: http://viam-works.ru (accessed: April 04, 2019).
10. Rubber compositions containing ethylene-propylene-diene terpolymers or ethylene-propylene copolymers and silicones: pat. US4341675A; filed 08.04.80; publ. 30.03.01.
11. Epdm and/or ethylene propylene and silicon rubber compositions: pat. CA1301982C; filed 30.03.87; publ. 26.05.09.
12. Silicon rubber/conductive ethylene propylene terpolymer rubber and its preparing method: pat. CN1186381C; filed 20.06.03; publ. 26.01.05.
13. Silicone rubber and terpolymer EP rubber blend and preparation method thereof: pat. CN103602067A; filed 20.10.13; publ. 26.10.14.
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Describes the modern methods of extracting carbon reinforcing fibers from polymer composite materials. The most popular methods are solvolysis and pyrolysis. Presents specific products from recycled carbon fiber and firms that specialize in this area of production. It is shown that the most popular method of manufacturing using recycled carbon fiber is 3D-printing from granules based on a thermoplastic polymer.
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The influence of condensation moisture of prepreg of carbon fiber reinforced plastic based on mortar epoxy resins on its reactivity and the properties of cured polymeric composite material was done, including the condensation moisture that is formed when conditions in the refrigerator or freezer are violated. Prepreg PU-4e-2m used in mass productionon the basis of a solution epoxy binder and carbon fiber reinforced plastic based on its KMU-4E-2m were considered as objects for research. Experimental DSC curves with detailed rheokinetic description the behavior of the analyzed prepregs were obtained. Properties of CFRP KMU-4e-2m based on thermostated and non-thermostated PU-4e-2m prepreg were investigated.
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This review on the modern devices of a x-ray difraktometry which are available on commercial sale in the territory of the Russian Federation, is prepared for research scientists and engineering personnel, students and postgraduate students. The review will be useful to the experts conducting researches and development in the field of metallurgy, materials science, technology of materials, a crystallography and solid state physics. The principal schemes and methods of diffraction experiments are considered, the technical characteristics and exterior of desktop x-ray diffractometers are presented.
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One of the main components of plastic waste is the polymer polyethylene terephthalate (PET), which causes a variety of environmental problems associated with its accumulation, sorption and concentration of organic pollutants, causing dangerous consequences for marine life, spreading potentially invasive species of microorganisms. The study of biocenoses formed on the surface of PET in various regions, industries, water bodies and other local objects, different environmental conditions, will significantly predict and prevent premature destruction of infrastructure under the influence of biological degradation and destruction of materials.
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