Articles
The analysis of Russian and foreign literature in aluminum high-end corrosion resistant alloys area was made. Base ways of development of these alloys are stated. Estimation of modern investigation level was made. The influence of alloying elements additions on microstructure, mechanical and fatique properties of Al–Mg–Si alloy was investigated. It was found that Ti and Zr gaves a positive effect for microstructure and mechanical properties.
2. Kablov E.N. Rossii nuzhny materialy novogo pokoleniya [Materials of new generation are necessary to Russia] // Redkie zemli. 2014. №3. S. 8–13.
3. Kablov E.N., Ospennikova O.G., Vershkov A.V. Redkie metally i redkozemelnye elementy – materialy sovremennyh i budushhih vysokih tehnologij [Rare metals and rare-earth elements are materials for modern and future high technologies] // Aviacionnye materialy i tehnologii. 2013. №S2. S. 3–10.
4. Kablov E.N., Startsev O.V., Medvedev I.M. Obzor zarubezhnogo opyta issledovanij korrozii i sredstv zashhity ot korrozii [Review of international experience on corrosion and corrosion protection] // Aviacionnye materialy i tehnologii. 2015. №2 (35). S. 76–87. DOI: 10.18577/2071-9140-2015-0-2-76-87.
5. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsij, tekhnologicheskogo liderstva i natsionalnoj bezopasnosti Rossii [Materials of new generation – basis of innovations, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. № 2 (14). S. 16–21.
6. Klochkov G.G., Grushko O.E., Popov V.I., Ovchinnikov V.V., Shamraj V.F. Struktura, tehnologicheskie svojstva i svarivaemost listov iz splava V-1341 sistemy Al–Mg–Si [Structure, technological properties and bondability of sheets from alloy V-1341 of Al–Mg–Si system] // Aviacionnye materialy i tehnologii. 2011. №1. S. 3–8.
7. Voronkov V.I., Potapenko K.E., Petrov P.A., Vydumkina S.V. Poluchenie utochnennykh dannykh po soprotivleniyu plasticheskoj deformatsii pri goryachej obemnoj shtampovke alyuminievykh splavov AD35 i AD31 [Obtaining specified data on plastic deformation resistance of aluminum alloys AD35 and AD31 at hot forging] // Aviacionnye materialy i tehnologii. 2017. №1 (46). S. 3–10. DOI: 10.18577/2071-9140-2017-0-1-3-10.
8. Splav na osnove alyuminiya i izdelie, vypolnennoe iz nego: pat. 2215055 Ros. Federatsiya. №2001133680 [Alloy on the basis of aluminum and the product which has been executed of it: pat. 2215055 Rus. Federation. No. 2001133680]; zayavl. 17.12.01; opubl. 27.10.03.
9. Deformiruemyj splav na osnove alyuminiya i izdelie, vypolnennoe iz etogo splava: pat. 2255133 Ros. Federatsiya. №2003136632 [Deformable alloy on the basis of aluminum and the product executed from this alloy: pat. 2255133 Rus. Federation. No. 2003136632]; zayavl. 19.12.03; opubl. 27.06.05.
10. Sposob proizvodstva pressovannykh izdelij iz alyuminievogo splava serii 6000: pat. 2542183 Ros. Federatsiya. №2013131745 [Way of production of the pressed products from aluminum alloy of series 6000: pat. 2542183 Rus. Federation. No. 2013131745]; zayavl. 09.07.13; opubl. 20.02.15.
11. Edwards G.A., Stiller K., Dunlop G.L., Couper M.J. The precipitation sequence in Al–Mg–Si alloys // Acta Materialia. 2010. Vol. 46. P. 3893–3904.
12. Pogatscher S., Antrekowitsch H., Leitner H. et al. Mechanisms controlling the artificial aging of Al–Mg–Si Alloys // Acta Materialia. 2011. Vol. 59. P. 3352–3363.
13. Chakrabarti D.J., Laughlin D.E. Phase relations and precipitation in Al–Mg–Si alloys with Cu additions // Progress in Materials Science. 2004. Vol. 49. P. 389–410.
14. Gupta A.K., Lloyd D.J., Court S.A. Precipitation hardening in Al–Mg–Si alloys with and without excess Si // Materials Science and Engineering. 2001. Vol. A316. P. 11–17.
15. Jacobs M.H. The structure of the metastable precipitates formed during ageing of an Al–Mg–Si alloy // Philosophical Magazine. 1972. Vol. 26 (1). P. 1–13.
16. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
Despite keen interest of designers in polymeric composite materials (PСM), aluminum alloys are the base constructional material of the aviation industry. The special attention is given to designs with high specific mechanical properties which treats aluminum cellular fillers. In work will mention question of protection of such materials from corrosion and giving of their surface of special properties with use of different ways of processing (pikling-process, sedimentation titanium oxide, sedimentation of aluminum oxide, MDO (micro-arc oxidation), chemical oxidation). Comprehensive researches of aluminum foil are conducted and the most effective ways of surface preparation are chosen.
2. Kablov E.N. Strategicheskie napravleniya razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda [The strategic directions of development of materials and technologies of their processing for the period to 2030] // Aviacionnye materialy i tehnologii. 2012. №S. S. 7–17.
3. Kablov E.N. Materialy novogo pokoleniya [Materials of new generation] // Zashchita i bezopasnost. 2014. №4. S. 28–29.
4. Kolobova Z.N., Pavlovskaya T.G., Anikhovskaya L.I., Karimova S.A. Razrabotka sposobov podgotovki poverkhnosti pri remonte kleenykh konstruktsij iz alyuminievykh splavov [Development of ways of surface preparation at repair of kleeny designs from aluminum alloys] // Aviacionnye materialy i tehnologii. M.: VIAM, 2002. Vyp.: Remontnye tekhnologii v aviastroenii. S. 73–76.
5. Antipov V.V. Strategiya razvitiya titanovyh, magnievyh, berillievyh i alyuminievyh splavov [Strategy of development of titanium, magnesium, beryllium and aluminum alloys] // Aviacionnye materialy i tehnologii. 2012. №S. S. 157–167.
6. Kablov E.N. Korroziya ili zhizn [Corrosion or life] // Nauka i zhizn. 2012. №11. S. 16–21.
7. Anikhovskaya L.I., Pavlovskaya T.G., Dementeva P.A., Petrova A.P. Podgotovka poverkhnosti pod skleivanie [Surface preparation under pasting] // Klei. Germetiki. Tekhnologii. 2008. №7. S. 32–35.
8. Pavlovskaya T.G., Volkov I.A., Kozlov I.A., Naprienko S.A. Ekologicheski uluchshennaya tehnologiya obrabotki poverhnosti alyuminievyh splavov [Ecologically improved technology of aluminum alloys surface treatment] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2016. №7. St. 02 (accessed: June 25, 2018). DOI: 10.18577/2307-6046-2016-0-7-2-2.
9. Illarionov E.I., Kolobnev N.I., Gorbunov P.Z., Kablov E.N. Alyuminievye splavy v aviakosmicheskoj tekhnike [Aluminum alloys in aerospace equipment]. M.: Nauka, 2001. 192 s.
10. Kulyushina N.V., Kozlov I.A., Kutyrev A.E., Vagramyan T.A. Adhesive coatings on the basis of trialkoxysilanes for aluminum and steel // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №8. St. 05. Available at: http://viam-works.ru (accessed: June 25, 2018). DOI: 10.18577/2307-6046-2015-0-8-5-5.
11. Skopintsev V.D. Oksidirovanie alyuminiya i ego splavov [Oxidation of aluminum and its alloys]. M.: RKhTU im. D.I. Mendeleeva, 2015. 120 s.
12. Vojtovich V.A. Sposoby podgotovki poverkhnosti izdelij iz metallov i splavov [Ways of surface preparation of products from metals and alloys] // Klei. Germetiki. Tekhnologii. 2005. №9. S. 19–23.
13. Ebnesajjad S. Handbook of adhesives and surface preparation. Technology, Applications and Manufacturing. William Andrew Publishing, 2011. 450 p. DOI: 10.1016/C2010-0-65918-9.
14. Ufferman B., Abke T., Barker M. et al. Mechanical properties of joints in 5052 aluminum made with adhesive bonding and mechanical fasteners // International Journal of Adhesion and Adhesives. 2018. Vol. 83. P. 96–102.
15. Chuang Gao, Long Li, Xin Chen et al. The effect of surface preparation on the bond strength of Al–St strips in CRB process // Materials & Design. 2016. Vol. 107. P. 205–211.
16. Keisuke Nagato, Takumu Yamaguchi, Masayuki Nakao. Anchoring and chemical-bonding effects of anodic alumina microstructure on adhesion strength // CIRP Annals. Available at: http://www.cirp.net (accessed: June 25, 2018).
17. Karimova S.A., Kutyrev A.E., Pavlovskaya T.G., Zaharov K.E. Nizkotemperaturnoe uplotnenie anodno-oksidnyh pokrytij na detalyah iz alyuminievyh splavov [Low temperature sealing of anodic oxide coatings on parts of aluminum alloys] // Aviacionnye materialy i tehnologii. 2014. №4. S. 9–17. DOI: 10.18577/2071-9140-2014-0-4-9-17.
18. DeMejo L.P., Rimai D.S., Sharpe L.H. Fundamentals of Adhesion and Interfaces. London: Taylor & Francis, 1999. 201 p.
19. Kozlov I.A., Pavlovskaya T.G., Zakharov K.E., Volkov I.A. Ekologicheski uluchshennye tekhnologii podgotovki poverkhnosti alyuminievykh splavov [Ecologically improved technologies of surface preparation of aluminum alloys] // Adgezionnye materialy: sb. dokl. nauch.-tekhnich. konf. M.: VIAM. 2016. S. 13 (CD).
This work is devoted to the determination of the optimal technology for manufacturing castings from the АК7ч. alloy (Al–Si systems) by the method of investment casting. Data on the capabilities of the investment casting method are given. The data on the basic requirements for the ceramic shell, as well as the method of its production and application, are presented. An experiment was conducted to determine the required number of layers of ceramic coating for aluminum castings of various configurations. On the basis of the analysis of the results of the work, the optimal number of applied layers was chosen for the production of model blocks and the method of shell molding.
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3. Spetsialnye sposoby litya: spravochnik / pod obshch. red. V.A. Efimova [Special ways of molding: directory / gen. ed. by V.A. Efimov]. M.: Mashinostroenie, 1991. 436 s.
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13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
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Corrosion-resistant cast aluminum alloys are considered in the article. The information about their mechanical characteristics and properties is given. The article presents the results of experiments that were carried out with cast aluminum alloys with different magnesium content and additional alloying elements for corrosion resistance and their behavior in an aggressive environment. Advantages, disadvantages and peculiarities of already existing alloys are described, as well as ways to improve alloys. The problem of the low operating temperature of existing corrosion-resistant aluminum casting alloys is especially actual.
2. Duyunova V.A., Volkova E.F., Uridiya Z.P., Trapeznikov A.V. Dinamika razvitiya magnievyh i litejnyh alyuminievyh splavov [Dynamics of the development of magnesium and cast aluminum alloys] // Aviacionnye materialy i tehnologii. 2017. №S. S. 225–241. DOI: 10.18577/2071-9140-2017-0-S-225-241.
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5. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
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The paper presents the review of the technical level and development trends in the field of heat treatment of magnesium alloys is presented. It is shown that new magnesium alloys containing elements from the REE group are being developed, and the foundations of new technologies for their manufacture are being created, while the mechanism of the effect of heat treatment on the structure and strength properties of alloys is widely used. The dependence of the increase in the characteristics of magnesium alloys on the composition of a particular alloy with the application of certain heat treatment regimes is given.
2. Kablov E.N., Ospennikova O.G., Vershkov A.V. Redkie metally i redkozemelnye elementy – materialy sovremennyh i budushhih vysokih tehnologij [Rare metals and rare-earth elements are materials for modern and future high technologies] // Aviacionnye materialy i tehnologii. 2013. №S2. S. 3–10.
3. Kornysheva I.S., Volkova E.F., Goncharenko E.S., Muhina I.Yu. Perspektivy primeneniya magnievyh i litejnyh alyuminievyh splavov [Perspectives of application of magnesium and cast aluminum alloys] // Aviacionnye materialy i tehnologii. 2012. №S. S. 212–222.
4. Volkova E.F. Analiz i itogi Mezhdunarodnoj konferencii «Magnij–21. Novye gorizonty» (obzor) [The analysis and results of the International conference «Magnesium–21. Broad horizons» (review)] // Aviacionnye materialy i tehnologii. 2016. №1 (40). S. 86–94. DOI: 10.18577/2071-9140-2016-0-1-86-94.
5. Kablov E.N. Materialy i khimicheskie tekhnologii dlya aviatsionnoj tekhniki [Materials and chemical technologies for aviation engineering] // Vestnik Rossijskoj akademii nauk. 2012. T. 82. №6. S. 520–530.
6. Volkova E.F., Antipov V.V. Magnievye deformiruemye splavy [Magnesium deformable alloys] // Vse materialy. Entsiklopedicheskij spravochnik. 2012. №5. S. 20‒26.
7. Volkova E.F. Sovremennye deformiruemye splavy i kompozitsionnye materialy na osnove magniya [Modern deformable alloys and composite materials on the basis of magnesium] // Metallovedenie i termicheskaya obrabotka metallov. 2006. №11. S. 5–9.
8. Kablov E.N. Aviatsionnoe materialovedenie: itogi i perspektivy [Aviation materials science: results and perspectives] // Vestnik Rossijskoj akademii nauk. 2002. T. 72. №1. S. 3–12.
9. Duyunova V.A., Volkova E.F., Uridiya Z.P., Trapeznikov A.V. Dinamika razvitiya magnievyh i litejnyh alyuminievyh splavov [Dynamics of the development of magnesium and cast aluminum alloys] // Aviacionnye materialy i tehnologii. 2017. №S. S. 225–241. DOI: 10.18577/2071-9140-2017-0-S-225-241.
10. Volkova E.F., Duyunova V.A., Ioda E.N., Panteleev M.D. Osobennosti svarivaemosti novogo deformiruemogo magnievogo splava VMD16 [Features of bondability of new deformable VMD16 magnesium alloy] // Svarochnoe proizvodstvo. 2017. №6. S. 3–11.
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13. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
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17. Process for manufacturing hot-forged parts made of a magnesium alloy: pat. FR2904005 (A1); field: 25.01. 08; publ. 25.03.08.
18. Mostyaev I.V. RZE – faktor kachestvennogo povysheniya svojstv magnievyh splavov (obzor) [REE – quality factor increase properties of magnesium alloy (review)] // Trudy VIAM: elektron. nauch.-tehnich. zhurn. 2015. №7. St. 02. Available at: http://www.viam-works.ru (accessed: June11, 2018). DOI: 10.18577/2307-6046-2015-0-7-2-2.
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The influence of extra hydrogen doping on phase and structural transformations in high-strength VT23 alloy has been studied. The volume ratios of α- and β-phases have been defined for room temperature state in dependence on hydrogen amount and hydrogenating annealing temperature in the range from 650 to 800°C. A quantitative estimation of β-phase content and α-particles dimensions in VT23 alloy have been evaluated with hydrogenation parameters being in focus. It has been shown that the alloy contains approximately 30% (vol.) of β-phase in initial condition. Doping with 0,1% (wt.) of hydrogen results in β-phase volume fraction increase from 50% after hydrogenation at 650°C to 80% after hydrogenation at 800°C. The dimensions of α-particles within the mentioned conditions change from 0,6–1,2 to 1,8–2,2 µm.
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The influence of extra hydrogen doping on processing ductility and crystallographic texture in high-strength VT23 alloy (Ti–4,5Al–4,0V–1,8Mo–0,86Cr–0,44Fe, % (wt.)) has been studied. The optimal hydrogenating annealing parameters have been developed for 1,8 mm thickness sheet semi-products (doping with 0,1% H (wt.) at a temperature of 750°C), which are favorable for room temperature processing ductility increase and achievement of the following ultimate tensile strength values: 1050 MPa for the rolling direction, and 1110 MPa for the transverse direction. It has been shown that hydrogenation causes no effect on texture type which had formed on the sheets production stage. The higher strength values in transverse direction are accounted for the location of basal planes {00.2} wherein sliding is difficult.
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The effect of different graphite grades in the copper-based metallic composite material on its tribotechnical properties is considered. Graphites were used as a solid lubricant with different crystal structure: synthetic, coarse-grained and fine-crystalline sintered, and finely dispersed colloidal. Tribotechnical tests data, according to the «finger–disk» testing scheme, have determined the influence of various sliding speeds and contact loading on the wear and friction coefficient depending on the graphite grades in composite material. It was shown that the tested graphite grades possess different tribotechnical properties associated with its manufacturing, dispersion and grain fineness.
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Hybrid GFRPs based on epoxy binder modified with carboxy-functionalized carbon nanotubes (CNTs) were synthesized, with CNT content in the 1–8% range. The structure of nanocomposites and their electrical properties and electromagnetic shielding performance in cm wavelength range were investigated. It was found that electrodynamic properties of the nanocomposites depend strongly on the thermal treatment conditions. These CNT-nanocomposites can be used as shielding materials for electromagnetic compatibility applica-tions.
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In article results of research of tribological properties of model systems of nonskid coatings based on one-component alkyd binding filled with a sand and an electrocorundum of different fractional structure. In work values of friction coefficient of the specified model systems, as are given in dry condition, and «drowned» in water. Submitted data can be used when developing nonskid coatings which are actively applied, both in the aviation industry, and in other spheres of national economy. Importance of assessment of tribological characteristics of systems in presence of water is defined by that the greatest danger to the personnel at operation of different objects is represented by wet surfaces, both after rain, and after spill of different liquids among which aqueous solutions and suspensions are the most widespread. In work attempt to explain the received results from the point of view of modern tribological theories is made.
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The results of a study of the susceptibility to crevice corrosion of aluminum alloys AMg6, D16-T and stainless steel 08X17 in tests in the natural sea water of the Black Sea are presented. The estimation of changes in appearance of samples, metallographic analysis and estimation of the degree of biofouling is carried out. Physico-chemical indicators of sea water, including those determined by capillary electrophoresis, are presented. The analysis of corrosion resistance tests in seawater, the features of the methodology for slit corrosion testing, and the mechanism of crevice corrosion formation are presented.
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Aggressive environments that lead to the occurrence of corrosion lesions of structures lead to significant changes in their mechanical characteristics and lead to a significant reduction in their bearing capacity and a decrease in durability. The danger of aggressive media exposure to highly loaded material is also due to the fact that in some cases the structural elements fail in a very short time, including with an emergency outcome. In the present work, the literature data, normative documentation and studies on the stress-corrosion cracking and loading methods of the test samples during the tests are analyzed. Particular attention is paid to tests with constant deformation, as the most common and least expensive test group and testing of samples under constant load. Recommendations are given on the timing of testing for stress-corrosion cracking of various metals and alloys.
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