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dx.doi.org/ 10.18577/2307-6046-2023-0-5-3-20

УДК 669.245

Petrushin N.V., Rimsha E.G., Lutskaya S.A., Dmitriev N.S.

DESIGN OF CORROSION-RESISTANT NICKEL-BASED SUPERALLOY VZHM9 FOR SINGLE CRYSTAL GAS TURBINE BLADES

The chemical composition and mechanical properties of the well-known corrosion-resistant nickel-based superalloys for of turbine blades with a columnar granular structure and a single-crystal structure are considered. Result of computer design and experimental studies of new single crystal corrosion resistant nickel-based superalloy VZHM9 with 1.5 (% wt.) Re and density 8.35 g/cm³ are presented. It is shown that the VZHM 9 alloy has high phase stability, increased tensile strength and ductility characteristics ( ), and creep strength ( ).

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Reference list

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dx.doi.org/ 10.18577/2307-6046-2023-0-5-21-32

УДК 539.26

Kuzmina N.A.

DEVELOPMENT OF X-RAY DIFFRACTION ANALYSIS IN VIAM On the 130th anniversary of the birth of E.F. Bakhmetev, the first head of the х-ray laboratory of the institute

Presents the history of the development of х-ray diffraction analysis in VIAM in different periods of the institute's existence. The article describes the activities of the first head of the х-ray Laboratory, Evgeny Fedorovich Bakhmetev, an outstanding specialist in the field of х-ray structural research of metals and alloys, the founder and developer of the theory of metal recrystallization. The development of х-ray research equipment is traced in the historical context of the tasks of developing new materials and methods for controlling the structure of alloys.

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Reference list

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24. Kuzmina N.A., Pyankova L.A. Control of crystallographic orientation of monocrystalline nickel castings heat-resistant alloys by х-ray diffractometry. Trudy VIAM, 2019, no. 12 (84), paper no. 02. Available at: http://www.viam-works.ru (accessed: October 12, 2022). DOI: 10.18577/2307-6046-2019-0-12-11-19.
25. Kablov E.N., Bondarenko Yu.A., Kablov D.E. Features of structure and heat resisting properties of monocrystals of <001> high-rhenium nickel hot strength alloys received in the conditions of high-gradient directed crystallization. Aviacionnye materialy i tehnologii, 2011, no. 4, pp. 25–31.
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28. Bondarenko Yu.A., Bazyleva O.A., Echin A.B., Surova V.A., Narsky A.R. High-gradient directional crystallization of parts from alloy VKNA-1V. Liteynoe proizvodstvo, 2012, no. 6, pp. 12–16.
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dx.doi.org/ 10.18577/2307-6046-2023-0-5-33-42

УДК 669.018.292

Antipov V.V., Panteleev M.D., Sviridov A.V., Skupov A.A., Odintsov N.S.

HEAT-RESISTANT ALUMINUM ALLOYS 1151 AND B-1213 WELDED FUSELAGE PANELS FABRICATION AND TESTING

The welded joints heat-resistant aluminum alloys V-1213 and 1151 were researched. The welded joints were performed according to the tested modes on the Laser Weld 8R60 laser welding complex. The properties joints, provided within ones and twice welding were given. The strength level of welded fuselage elements with an intermittent asymmetrical seam; with an intermittent symmetrical seam, with a continuous seam is investigated. The tests results of welded stringer panels with the bearing capacity determination during shear are presented.

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dx.doi.org/ 10.18577/2307-6046-2023-0-5-43-53

УДК 66.017

Kuznetcova P.A., Tkachuk A.I., Lyubimova A.S., Eldjaeva G.B.

CHARACTERISTICS OF THE MOLTEN EPOXY RESIN SYSTEM VSE-62, PROCESSED BY THE INJECTION METHODS, FOR THE MANUFACTURE OF HIGHLY LOADED STRUCTURAL POLYMER COMPOSITE MATERIALS

In the present work, the thermophysical and physicomechanical characteristics of a molten epoxy resin system VSE-62, developed in SIC «Kurchatov Institute» – VIAM, are considered. The value of the glass transition temperature of the system, the kinetic parameters of the curing process with a different speed of the heating, the plot of the gelation time and flexural strength are given. The results of rheological tests in isothermal and dynamical modes are shown. The low viscosity of the system and long-term viability at high temperatures allows it to be used for the manufacture of various polymer composite materials by resin transfer moulding and vacuum assisted resin transfer moulding.

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19. Kablov E.N., Laptev A.B., Prokopenko A.N., Gulyaev A.I. Relaxation of polymeric composite materials under the prolonged action of static load and climate (review). Part 1. Binders. Aviation materials and technologies, 2021, no. 4 (65), paper no. 08. Available at: http://www.journal.viam.ru (accessed: October 15, 2022). DOI: 10.18577/2071-9140-2021-0-4-70-80.
20. Mukhametov R.R., Petrova A.P. Thermosetting binders for polymer composites (review). Aviacionnye materialy i tehnologii, 2019, no. 3 (56), pp. 48–58. DOI: 10.18577/2071-9140-2019-0-3-48-58.
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22. Kladovshchikova O.I., Tikhonov N.N., Zhdanov I.A., Sutyagina A.K., Nakhaeva A.V. Composite materials based on ultra-high molecular weight polyethylene. Uspekhi v khimii i khimicheskoy tekhnologii, 2019, vol. 3, no. 6, pp. 30–32.
23. Lubin. J. Handbook of composite materials. Moscow: Mashinostroenie, 1988, 348 p.

dx.doi.org/ 10.18577/2307-6046-2023-0-5-54-63

УДК 621.792.053

Lukina N.F., Isaev A.Yu., Starodubtseva О.А., Balabanova O.S.

APPROACHES TO CREATION OF CONDUCTING GLUE FROM THE LOWERED CURING TEMPERATURE

Properties of pilot conducting glue with ponidenny temperature of curing are considered. According to the destination pilot glue is close to conducting glue of the VKP-11 brand of similar assignment. Advantage of pilot glue is the lowered temperature of curing (60 °C instead of 120 °C for VKP-11 glue). Properties of the pilot conducting glue containing in the structure carbonyl nickel as conducting filler, in the range of temperatures from –60 to +120 °C in initial condition and after influence of artificial external factors are investigated.

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Reference list

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2. Kablov E.N. Materials for aerospace engineering. Vse materialy. Entsiklopedicheskiy spravochnik, 2007, no. 5, pp. 7–27.
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13. Petrova A.P., Lukina N.F., Pavlyuk B.F., Isaev A.Yu., Besednov K.L. Fillers for conductive adhesives. Novosti materialovedeniya. Nauka i tekhnika, 2017, no. 5–6 (28), paper no. 06. Available at: http://www.materialsnews.ru (accessed: November 30, 2022).
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16. Lukin V.I., Rulnikov V.S., Afanasiev-Khodikin A.N., Kucevich K.E., Nischev K.N. The method for adhesion strength determining of silver coating to the silicon substrate by glue applying. Trudy VIAM, 2015, no. 4, paper no. 12. Available at: http://www.viam-works.ru (accessed: January 20, 2023). DOI: 10.18577/2307-6046-2015-0-4-12-12.
17. Kurilin S.L. Electrical materials and technologies of electrical work: allowance at 3 parts. Gomel: BelSUT. 2008, part 1: Conductor and semiconductor materials, 88 p.
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26. Malysheva G.V., Grashchenkov D.V., Guzeva T.A. Evaluation of technological use efficiency of adhesives and glue prepregs in the manufacture of three-layer panels. Aviacionnye materialy i tehnologii, 2018, no. 4 (53), pp. 26–30. DOI: 10.18577/2071-9140-2018-0-4-26-30.
27. Bolshakov V.A., Antyufeeva N.V. Investiga-tion of the modification shungite of carbon plastic on the basis of epoxy matrix. Trudy VIAM, 2018, no. 3 (63), paper no. 12. Available at: http://www.viam-works.ru (accessed: January 17, 2023). DOI: 10.18577/2307-6046-2018-0-3-103-110.
28. Isaev A.Yu., Rubtsova E.V., Kotova E.V., Sutyagin M.N. Research of properties of glues and glue binding, made with use of modern domestic component base. Trudy VIAM, 2021, no. 3 (97), paper no. 05. Available at: http://www.viam-works.ru (accessed: January 25, 2023). DOI: 10.18577/2307-6046-2021-0-3-58-67.
29. Volkov A.V., Moskvina M.A., Karachevtsev I.V. Structure and electrical conductivity of highly dispersed polymer compositions – CuS, obtained in situ. Vysokomolekulyarnye soyedineniya. Seriya A, 1998, vol. 40, no. 6, pp. 970–976.

dx.doi.org/ 10.18577/2307-6046-2023-0-5-64-74

УДК 678.8

Karavaev R.Y., Gorodilova N.A., Donetskiy K.I.

PRODUCTION OF POLYMER COMPOSITE MATERIALS BASED ON SEMIPREGS

The features of manufacturing polymer composite materials (PCM) based on semipregs processed by vacuum molding are considered. The main approaches and requirements for binders, fillers and processes taking place during molding are established. Attention is drawn to the research carried out by foreign manufacturers of semipregs. Darcy's law is presented as the main postulate when carrying out the processes of impregnation of fillers with a binder. The properties of PCM based on semipregs made of equal-strength and unidirectional fabrics and epoxy melt binder developed by SIC «Kurchatov Institute» – VIAM are given.

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Reference list

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dx.doi.org/ 10.18577/2307-6046-2023-0-5-75-84

УДК 621.763

Antipov V.V., Stepanova E.V., Babashov V.G., Ivakhnenko Yu.A., Butakov V.V.

INFLUENCE OF REINFORCEMENT WITH OXIDE REFRACTORY FIBERS ON THE FLEXIBILITY OF THERMAL INSULATION MATERIALS

In this work, we investigated the possibility of improving the flexibility of sealing heat-insulating materials by introducing a reinforcing component into the composition of the material in the form of chopped oxide ceramic refractory fibers. The effect of a reinforcing component on the change in the critical bending radius of samples of fibrous material based on ceramic refractory fibers has been studied. Sample tests showed an improvement in flexibility by 12–25 %, depending on the thickness and bulk density of heat-insulating materials.

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Reference list

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3. Onishchenko G.G., Kablov E.N., Ivanov V.V. Scientific and technological development of Russia in the context of achieving national goals: problems and solutions. Innovacii, 2020, no. 6 (260), pp. 3–16.
4. Kablov E.N. The role of fundamental research in the creation of new generation materials. Report XXI Mendeleev Congress on General and Applied Chemistry: in 6 vols. St. Petersburg, 2019, vol. 4, pp. 24.
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12. Zuev A.V., Zarichnyak Yu.P., Barinov D.Ya., Krasnov L.L. Measurement of thermophysical properties of flexible thermal insulation. Aviation materials and technology, 2021, no. 1 (62), paper no. 11. Available at: http://www.journal.viam.ru (accessed: October 31, 2022). DOI: 10.18577/2713-0193-2021-0-1-119-126.
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19. Perepelkin K.E. Reinforcing fibers and fibrous polymer composites. St. Petersburg: Nauchnye osnovy i tekhnologii, 2009, 380 p.
20. Method for obtaining fibrous oxide material: pat. SU 1730233 A1; filed 28.03.89; publ. 30.04.92.
21. Zhitnyuk S.V., Medvedev P.N., Sorokin O.Yu., Kachaev A.A. Formation of crystallographic texture in polycryctalline ceramics as a way to enhance properties (review). Trudy VIAM, 2022, no. 5 (111), paper no. 07. Available at: http://www.viam-works.ru (accessed: October 11, 2022). DOI: 10.18577/2307-6046-2022-0-5-74-86.
22. Stepanova E.V., Maksimov V.G., Ivakhnenko Yu.A. Internal defects of complex threads from oxide refractory fibers. Novye ogneupory, 2022, no. 2, pp. 56–60.
23. Butakov V.V., Basargin O.V., Babashov V.G., Ivakhnenko Yu.A. A behavioral model of the fibrous material during bending tests. Trudy VIAM, 2014, no. 12, paper no. 6. Available at: http://www.viam-works.ru (accessed: November 14, 2022). DOI: 10.18577/2307-6046-2014-0-12-6-6.
24. Kolyshev S.G., Basargin O.V., Butakov V.V. Experiments to determine the tensile strength of samples from lightweight flexible fibrous materials. Vse materialy. Entsiklopedicheskiy spravochnik, 2014, no. 5, pp. 8–11.
25. Duka A.V. Development of technology for improved quartz HSM based on the development of the principles of structure formation of fibrous pulps: thesis abstract, Cand. Sc. (Tech.). Moscow: VIAM, 1989, 22 p.
26. Khodakovsky M.D. Manufacture of glass fibers and fabrics. Moscow: Khimiya, 1973, 312 p.
27. Chernyak M.G. Continuous glass fiber. Moscow: Khimiya, 1965, 322 p.
28. Zhabin A.N., Sidorov D.V., Nyafkin A.N. Fibrous composite materials with a metal matrix (review). Trudy VIAM, 2021, no. 6 (100), paper no. 03. Available at: http://www.viam-works.ru (accessed: October 04, 2022). DOI: 10.18577/2307-6046-2021-0-6-27-35

dx.doi.org/ 10.18577/2307-6046-2023-0-5-85-93

УДК 678.8

Savitsky R.S., Sudyin Yu.I., Salakhova R.K.

COMPARISON OF THE EFFECT OF DIFFERENT RELEASE AGENTS ON THE FREE SURFACE ENERGY OF POLYMER TOOLING

Optimality of choice of an antiadhesive for a specific molding surface when molding products from polymer composite materials (PCM) is determined by many factors: absence of scratching of coating from the surface of tooling and of transfer of release agent to molded blank, ease of removal and defectlessness of the product from PCM. Offers an additional factor for evaluating the optimality of selecting an antiadhesive for polymer tooling: determination of free surface energy (FSE), which gives a characteristic of tooling surface wettability. In the framework of this work the FSEs of five different antiadhesion compositions were investigated.

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Reference list

1. Kablov E.N. Composites: today and tomorrow. Metally Evrazii, 2015, no. 1, pp. 36–39.
2. Kablov E.N. Materials and chemical technologies for aviation equipment. Vestnik Rossiyskoy akademii nauk, 2012, vol. 82, no. 6, pp. 520–530.
3. Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
4. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
5. Kablov E.N., Grashchenkov D.V., Isaeva N.V., Solntsev S.S., Sevastyanov V.G. High-Temperature Structural Composite Materials Based on Glass and Ceramics for Advanced Aircraft Products. Steklo i keramika, 2012, no. 4, pp. 7–11.
6. Tkachuk A.I., Donetsky K.I., Terekhov I.V., Karavaev R.Yu. The use of thermosetting matrices for the manufacture of polymer composite materials by the non-autoclave molding methods. Aviation materials and technology, 2021, no. 1 (62), paper no. 03. Available at: https://journal.viam.ru (accessed: November 16, 2022). DOI: 10.18577/2713-0193-2021-0-1-22-33.
7. Tkachuk A.I., Terekhov I.V., Gurevich Ya.M., Kudryavtseva A.N. Application of bismaleimide VST-57 binder for obtaining heat-resistant dimensionally stable molds from polymer composite materials. Aviacionnye materialy i tehnologii, 2020, no. 2 (59), pp. 32–40. DOI: 10.18577/2071-9140-2020-0-2-32-40.
8. Mosiyuk V.N., Tomchani O.V. Evaluation of properties of glass-fibre-reinforced plastics based on epoxybisma-leimide resin, produced by different non-autoclave molding techniques. Aviacionnye materialy i tehnologii, 2019, no. 2 (55), pp. 47–52. DOI: 10.18577/2071-9140-2019-0-2-47-52.
9. Kolpachkov E.D., Petrova A.P., Kurnosov A.O., Sokolov I.I. Methods of molding aviation products from PCM (review). Trudy VIAM, 2019, no. 11 (83), paper no. 03. Available at: http://www.viam-works.ru (accessed: November 16, 2022). DOI: 10.18577/2307-6046-2019-0-11-22-36.
10. Kablov E.N., Chursova L.V., Babin A.N., Mukhametov R.R., Panina N.N. Developments of FSUE "VIAM" in the field of melt binders for polymer composite materials. Polimernye materialy i tekhnologii, 2016, vol. 2, no. 2, pp. 37–42.
11. Mukhametov R.R., Petrova A.P., Ponomarenko S.A. Anti-adhesive coatings and their properties. Trudy VIAM, 2018, no. 12 (72), paper no. 10. Available at: http://www.viam-works.ru (accessed: November 16, 2022). DOI: 10.18577/2307-6046-2018-0-12-88-96.
12. Semenova L.V., Novikova T.A., Nefedov N.I. Study of removing ability of removers for paint systems removal. Aviacionnye materialy i tehnologii, 2017, no. 1 (46), pp. 32–37. DOI: 10.18577/2071-9140-2017-0-1-32-37.
13. Frolov V.I., Semenov A.P., Grishina I.N., Kucherov V.G. Wetting angle and methods for its determination. Moscow: Publishing Center of the Russian State University of Oil and Gas (NRU) im. I.M. Gubkina, 2021, 53 p.
14. Zinina I.N., Pimanov M.V. Influence of the surface energy of metal samples on the strength of adhesive joints. Izvestiya MSTU "MAMI", 2011, no. 2 (21), pp. 127–130.
15. Yakovets N.V., Krutko N.P., Opanasenko O.N. Determination of the free surface energy of powdered resinous-asphalten substances by the Owens–Wendt–Rabel–Kaelble method. Sviridovskie chteniya, 2012, no. 8, pp. 253–260.

dx.doi.org/ 10.18577/2307-6046-2023-0-5-94-110

УДК 539.612

Marchenko S.A., Zheleznyak V.G., Kuznetsova V.A.

APPLICATION AND MODIFICATION OF PARTICLES TO CREATE SUPERHYDROPHOBIC COATINGS (review)

Superhydrophobic polymer coatings arouse considerable interest in their industrial application, and the development of nanotechnology has simplified the development and production of nanotextured superhydrophobic coatings. Currently, the presence of functional particles/nanoparticles in its composition is a prerequisite for obtaining most superhydrophobic coatings, and the main problem of such coatings is low stability, which affects their practical application. The review is devoted to the analysis of the latest trends in the use of micro- and nanoparticles for the formation of superhydrophobic coatings, modification of particles and methods of their introduction into the coating.

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Reference list

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10.

dx.doi.org/ 10.18577/2307-6046-2023-0-5-111-123

УДК 620.179

Boychuk A.S., Dikov I.A., Chertishchev V.Yu., Generalov A.S., Gorbovets M.A.

ULTRASONIC TESTING OF CFRP MONOLITH STRUCTURES RADIUS ZONES BY RADIUS PHASED ARRAY AND SPECIAL DEVICE

The paper is devoted to nondestructive testing of CFRP monolithic structures radius zones. Manual ultrasonic testing technique by radius phased array and special device is proposed by the authors. Technique allows non-destructive testing of such zones with different radii and bending angles of structures from the inside without testing object immersing in a water container. Technique makes it possible to detect flat defects in radius zones such as extraneous inclusions and voids with diameter from 3 mm and a signal-to-noise ratio of more than 10 dB.

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Reference list

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21. Kablov E.N. The strategic directions of development of materials and technologies of their processing for the period to 2030. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 7–17.
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11.

dx.doi.org/ 10.18577/2307-6046-2023-0-5-124-133

УДК 543.51; 669.1

Alekseev A.V., Petrov P.S.

DETERMINATION OF IMPURITIES IN NICKEL ALLOYS BY THE METHOD OF PARK OPTICAL EMISSION SPECTROSCOPY

Impurities (the concentration of most elements is less than 0,01 % wt.) As, Ca, Zr, Pb, Nb, La, Nd and Fe in a nickel alloy were determined by spark optical emission spectroscopy (ISES). The equipment settings were selected to maximize the analytical signals from all the elements being determined. The analysis was carried out without the use of standard samples using the calibration dependences embedded in the software of the equipment. The correctness of the obtained results was confirmed by a comparative analysis by inductively coupled plasma mass spectrometry.

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Reference list

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dx.doi.org/ 10.18577/2307-6046-2023-0-5-134-144

УДК 543.51; 669.1

Alekseev A.V., Yakimovitch P.V., Koshelev A.V.

ANALYSIS OF ALUMINUM BY GLOW DISCHARGE HIGH RESOLUTION MASS SPECTROMETRY

In this work, the impurities of 72 elements in high purity (4N) aluminum were determined by the method of high-resolution glow discharge mass spectrometry (GDMS). The most suitable sample preparation was selected, including preliminary acid etching of the sample. To achieve the maximum analytical signals from all the required elements, the appropriate equipment settings were selected. Relative sensitivity coefficients (RCF) were calculated for all the elements being determined using a standard aluminum sample.

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CONTENТS

Heat-resistant alloys and steels

Petrushin N.V., Rimsha E.G., Lutskaya S.A., Dmitriev N.S. Design of corrosion-resistant nickel-based superalloy VZHM9 for single crystal gas turbine blades

Kuzmina N.A. Development of x-ray diffraction analysis in VIAM. On the 130th anniversary of the birth of E.F. Bakhmetev, the first head of the х-ray laboratory of the institute

Light-metal alloys

Antipov V.V., Panteleev M.D., Sviridov A.V., Skupov A.A., Odintsov N.S. Heat-resistant aluminum alloys 1151 and B-1213 welded fuselage panels fabrication and testing

Polymer materials

Kuznetcova P.A., Tkachuk A.I., Lyubimova A.S., Eldjaeva G.B. Characteristics of the molten epoxy resin system VSE-62, processed by the injection methods, for the manufacture of highly loaded structural polymer composite materials

Lukina N.F., Isaev A.Yu., Starodubtseva О.А., BalabanovаО.S. Approaches to creation of conducting glue from the lowered curing temperature

Composite materials

Karavaev R.Yu., Gorodilova N.A., Donetskiy K.I. Production of polymer composite materials based on semipregs

Antipov V.V., Stepanova E.V., Babashov V.G.,Ivakhnenko Yu.A., Butakov V.V. Influence of reinforcement with oxide refractory fibers on the flexibility of thermal insulation materials

Savitsky R.S., Sudin Yu.I., Salakhova R.K. Comparison of the effect of different release agents on the free surface energy of polymer tooling

Protective and functional

coatings

Marchenko S.A., Zheleznyak V.G., Kuznetsova V.A. Application and modification of particles to create superhydrophobic coatings (review)

Material tests

Boychuk A.S., Dikov I.A., Chertishchev V.Yu., Generalov A.S., Gorbovets M.A. Ultrasonic testing of CFRP monolith structures radius zones by radius phased array and special device

Alekseev A.V., Petrov P.S. Determination of impurities in nickel alloys by the method of park optical emission spectroscopy

Alekseev A.V., Yakimovich P.V., Koshelev A.V. Analysis of aluminum by glow discharge high resolution mass spectrometry

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